Synthesis, characterization, photophysical and photochemical properties of zinc and indium phthalocyanines bearing a vanillylacetone moiety known as an anticarcinogenic agent

Kiyak, Bülent; Esenpinar, Aliye; Bulut, Mustafa

doi:10.1016/j.poly.2015.01.043

Synthesis, characterization, photophysical and photochemical properties of zinc and indium phthalocyanines bearing a vanillylacetone moiety known as an anticarcinogenic agent

Kiyak B., Esenpinar A. A., Bulut M.

Polyhedron, cilt.90, ss.183-196, 2015 (SCI-Expanded, Scopus)

Yayın Türü: Makale / Tam Makale
Cilt numarası: 90
Basım Tarihi: 2015
Doi Numarası: 10.1016/j.poly.2015.01.043
Dergi Adı: Polyhedron
Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
Sayfa Sayıları: ss.183-196
Anahtar Kelimeler: Zingerone, Vanillylacetone, Phthalocyanine, Fluorescence quenching, Singlet oxygen
Kırklareli Üniversitesi Adresli: Evet

Özet

The synthesis of novel peripherally/non-peripherally tetra and octa vanillylacetone-substituted zinc and indium phthalocyanines was performed by cyclotetramerization of 4-[2-methoxy-4-(3-oxobutyl)phenoxy]phthalonitrile (1)/3-[2-methoxy-4-(3-oxobutyl)phenoxy]phthalonitrile (2) and 4,5-bis[2-methoxy-4-(3-oxobutyl)phenoxy]phthalonitrile (3). The novel chromogenic compounds were characterized by elemental analysis, 1H NMR, mass spectra, FT-IR and UV-Vis spectral data. The effects of the zingerone units on the zinc and indium phthalocyanine complexes (4-9) were also investigated.